Jembo said:I paid for my last two new cars on a debit card which took money directly from my current account and credited theirs immediately.
The only thing u may have to do is tell the Bank in advance the day & beneficiary, just so none of their fraud prevention kicks in.
I did the same, called the bank first, they asked some security questions (exact amount, who the payment is to etc) and then gave me a 30 min window to do the transaction. I guess they tell their fraud prevention to calm down for 30 mins or so.