Hi, I have been reading the forum for ages and will be buying a Z4C soon, but your question made me sign up. Supermarket fuel is purchased on the 'spot' market. This is basically, the supermarket buyers purchase it from a wide range of sources, a lot of which is produced in Eastern Europe etc. This is not a problem but the spec maybe sightly relaxed.
The bigger difference is using 'super' unleaded vs unleaded. Super unleaded usually has, in the UK, up to 20% methanol. Again not an issue, in fact a great improvement. But if you don't use the car every day its a waste of money, as methanol will evaporate quicker than the other MOGAS components. Also it attracts water which causes the fuel to appear cloudy.
There is a water spec on MOGAS which is tested before the fuel can be sold, If you consider the amount of transfers the fuel must make before it makes it into your fuel tank the possibility of water contamination is quite high.
Production
Storage within refinery (separate components)
Storage within refinery (Final product)
(If coming from abroad) Ship Tanks
Road Tanker
Petrol station underground tanks
Your fuel tank.
Super Unleaded also stays in the forecourt tanks longer as it is less popular.
It's better fill up when the temp is lower as the fuel is a little more dense at low temperatures!
Fuel produced in the UK is better for your car, and your countries economy.
Do I use supermarket fuel??
Course I do its cheaper!!
And I drive a diesel at the moment!
Sorry for the rant and welcome.
Am I as boring as I think I am??