The question of 'is it worth it?' Probably depends on if you think there are any weaknesses with the brakes you already have. Bigger discs won't really make the car stop any quicker - if that's your goal then would be more cost effective to buy better brake pads with more bite.
Bigger discs will dissipate heat more, so if you do track work, then yes, definitely worth it for sustained stopping power. On the road in everyday driving, probably not worth it.
Bigger discs do look better too, if that's important.